OPTIMAL CONDITIONS FOR EXTRACTION OF VALUABLE COMPONENTS FROM RICE HUSK
DOI:
https://doi.org/10.5281/zenodo.22835071Abstract
The optimal technological parameters for the complex extraction of cellulose, lignin, and silica through the alkaline treatment of rice husk were determined. The effects of sodium hydroxide (NaOH) concentration, treatment temperature, and processing duration on process efficiency were experimentally evaluated. The results demonstrated that the optimal process conditions were achieved at a rice husk-to-solution ratio of 1:10, a NaOH concentration of 15%, a treatment temperature of 120 °C, and a processing duration of 120 minutes. Under these conditions, up to 93% of the inorganic components were dissolved, while the cellulose yield reached 35%. The extracted cellulose was identified as a promising raw material for nanocellulose production, whereas lignin and silica demonstrated considerable potential for applications in the chemical, construction, and composite materials industries. The obtained results provide a scientific and practical basis for developing resource-efficient and environmentally friendly technologies for the complex processing of rice husk and the production of high-value-added products from agricultural waste.Keywords
rice husk, lignocellulosic biomass, cellulose, lignin, silicon dioxide, sodium hydroxide, alkaline treatment, technological optimization, nanocelluloseReferences
Habibi, Y., Lucia L., A., & Rojas O., J. (2010). Cellulose nanocrystals: Chemistry, self-assembly, and applications. Chemical Reviews, 110(6), 3479–3500. https://doi.org/10.1021/cr900339w
Klemm, D., Kramer, F., Moritz, S., Lindström, T., Ankerfors, M., Gray, D., & Dorris, A. (2011). Nanocelluloses: A new family of naturebased materials. Angewandte Chemie International Edition, 50(24), 5438–5466. https://doi.org/10.1002/anie.201001273
Moon R., J., Martini, A., Nairn, J., Simonsen, J., & Youngblood, J. (2011). Cellulose nanomaterials review: Structure, properties and nanocomposites. Chemical Society Reviews, 40, 3941–3994. https://doi.org/10.1039/C0CS00108B
Isogai, A., Saito, T., & Fukuzumi, H. (2011). TEMPO-oxidized cellulose nanofibers. Nanoscale, 3, 71–85. https://doi.org/10.1039/C0NR00583E
Klemm, D., Schumann, D., Kramer, F., Hessler, N., Hornung, M., Schmauder H., P., & Marsch, S. (2006). Nanocelluloses as innovative polymers in research and application. Advances in Polymer Science, 205, 49–96. https://doi.org/10.1007/3-540-31250-3_2
Brinchi, L., Cotana, F., Fortunati, E., & Kenny J., M. (2013). Production of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications. Carbohydrate Polymers, 94(1), 154–169. https://doi.org/10.1016/j
Trache, D., Hussin M., H., Haafiz M. K., M., & Thakur V., K. (2017). Recent progress in cellulose nanocrystals: Sources and production. Nanoscale, 9, 1763–1786. https://doi.org/10.1039/C6NR09494E
Rosa M., F., Medeiros E., S., Malmonge J., A., Gregorski K., S., Wood D., F., Mattoso L. H., C., Orts W., J., & Imam S., H. (2010). Cellulose nanowhiskers from coconut husk fibers: Effect of preparation conditions on their thermal and morphological behavior. Carbohydrate Polymers, 81(1), 83–92. https://doi.org/10.1016/j.carbpol.2010.01.059
Mandal, A., & Chakrabarty, D. (2011). Isolation of nanocellulose from waste sugarcane bagasse and its characterization. Carbohydrate Polymers, 86(3), 1291–1299. https://doi.org/10.1016/j.carbpol.2011.06.030
Lu, P., & Hsieh Y., L. (2012). Preparation and characterization of cellulose nanocrystals from rice straw. Carbohydrate Polymers, 87(1), 564–573. https://doi.org/10.1016/j.carbpol.2011.08.070
Johar, N., Ahmad, I., & Dufresne, A. (2012). Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Industrial Crops and Products, 37, 93–99. https://doi.org/10.1016/j.indcrop.2011.12.016

